1 00:00:00,985 --> 00:00:03,280 The following content is provided under a Creative 2 00:00:03,280 --> 00:00:04,670 Commons license. 3 00:00:04,670 --> 00:00:06,880 Your support will help MIT OpenCourseWare 4 00:00:06,880 --> 00:00:10,970 continue to offer high-quality educational resources for free. 5 00:00:10,970 --> 00:00:13,540 To make a donation or to view additional materials 6 00:00:13,540 --> 00:00:17,500 from hundreds of MIT courses, visit MIT OpenCourseWare 7 00:00:17,500 --> 00:00:18,386 at ocw.mit.edu. 8 00:00:22,360 --> 00:00:24,510 MICHAEL SHORT: So since I know series decay is 9 00:00:24,510 --> 00:00:28,050 a difficult topic to jump into, I wanted to quickly re-go over 10 00:00:28,050 --> 00:00:30,900 the derivation today and then specifically go over 11 00:00:30,900 --> 00:00:34,110 the case of nuclear activation analysis, which reminds me, 12 00:00:34,110 --> 00:00:37,680 did you guys bring in your skin flakes and food pieces? 13 00:00:37,680 --> 00:00:38,222 We have time. 14 00:00:38,222 --> 00:00:40,555 So if you didn't remember, start thinking about what you 15 00:00:40,555 --> 00:00:41,933 want to bring in, what you got. 16 00:00:41,933 --> 00:00:42,760 AUDIENCE: Aluminum foil. 17 00:00:42,760 --> 00:00:43,890 MICHAEL SHORT: OK, so you've got aluminum foil. 18 00:00:43,890 --> 00:00:46,410 You want to see what in it is not aluminum-- excellent. 19 00:00:46,410 --> 00:00:48,102 Well, what else did folks bring in? 20 00:00:48,102 --> 00:00:49,102 AUDIENCE: [INAUDIBLE] 21 00:00:49,102 --> 00:00:50,560 MICHAEL SHORT: OK, rubber stopper-- 22 00:00:50,560 --> 00:00:52,140 sound perfect. 23 00:00:52,140 --> 00:00:54,040 Anyone else bring something in? 24 00:00:54,040 --> 00:00:55,920 AUDIENCE: [INAUDIBLE] 25 00:00:55,920 --> 00:00:59,970 MICHAEL SHORT: OK, so tell you what, when you bring stuff in, 26 00:00:59,970 --> 00:01:01,742 bring it in a little plastic baggie. 27 00:01:01,742 --> 00:01:03,450 I can supply those if you don't have them 28 00:01:03,450 --> 00:01:05,580 with your name on them just so we know whose samples are what 29 00:01:05,580 --> 00:01:07,290 because that's going to be the basis for another one 30 00:01:07,290 --> 00:01:08,530 of your homeworks where are you going 31 00:01:08,530 --> 00:01:10,350 to use the stuff that we're learning today 32 00:01:10,350 --> 00:01:14,870 to determine which impurities and how much are in whatever 33 00:01:14,870 --> 00:01:16,290 thing that you looked at. 34 00:01:16,290 --> 00:01:18,180 And, of course, you're not going to get all the impurities 35 00:01:18,180 --> 00:01:19,555 because in order to do that, we'd 36 00:01:19,555 --> 00:01:22,170 have to do a long nuclear activation analysis, 37 00:01:22,170 --> 00:01:24,873 irradiate for days, and count for a longer time. 38 00:01:24,873 --> 00:01:26,790 So you'll just be responsible for the isotopes 39 00:01:26,790 --> 00:01:29,390 on the shortlist, which we've posted on the learning module 40 00:01:29,390 --> 00:01:31,410 site. 41 00:01:31,410 --> 00:01:33,840 So again, bring in your whatever, 42 00:01:33,840 --> 00:01:36,480 as long as it's not hair because, apparently, that's 43 00:01:36,480 --> 00:01:40,350 a pain to deal with or salty because the sodium activates 44 00:01:40,350 --> 00:01:43,800 like crazy or fissionable, which you shouldn't have, anyway. 45 00:01:43,800 --> 00:01:46,890 I hope none of you have fissionable material at home. 46 00:01:46,890 --> 00:01:52,230 So let's get back into series decay. 47 00:01:52,230 --> 00:01:56,430 We very quickly went over the definition of activity 48 00:01:56,430 --> 00:01:59,460 which is just the decay constant times the amount of stuff 49 00:01:59,460 --> 00:02:01,200 that there is, the decay constants, 50 00:02:01,200 --> 00:02:04,160 and units of 1 over second. 51 00:02:04,160 --> 00:02:06,600 The amount of stuff-- let's call it 52 00:02:06,600 --> 00:02:12,780 a number density-- could be like an atoms per centimeter cubed, 53 00:02:12,780 --> 00:02:13,970 for example. 54 00:02:13,970 --> 00:02:17,670 So the activity would give you the amount of, 55 00:02:17,670 --> 00:02:22,845 let's say decays, per centimeter cubed per second. 56 00:02:22,845 --> 00:02:25,470 If you wanted to do this for an absolute amount of a substance, 57 00:02:25,470 --> 00:02:28,020 like you knew how much of the substance there was, 58 00:02:28,020 --> 00:02:30,180 you just ditched the volume. 59 00:02:30,180 --> 00:02:33,360 And you end up with the activity in decays per second. 60 00:02:33,360 --> 00:02:37,260 That unit is better known as becquerels or BQ, 61 00:02:37,260 --> 00:02:39,180 named after Henri Becquerel, though I don't 62 00:02:39,180 --> 00:02:40,080 know if I'm saying that right. 63 00:02:40,080 --> 00:02:41,700 But my wife's probably going to yell 64 00:02:41,700 --> 00:02:43,860 at me when she sees this video. 65 00:02:43,860 --> 00:02:45,090 But so becquerel is simple. 66 00:02:45,090 --> 00:02:47,550 It's simply 1 decay per second, and there's 67 00:02:47,550 --> 00:02:51,180 another unit called the curie, which is just a whole lot more 68 00:02:51,180 --> 00:02:52,080 decays per second. 69 00:02:52,080 --> 00:02:54,690 It's a more manageable unit of the case 70 00:02:54,690 --> 00:02:57,630 because becquerel-- the activity of many things in becquerels 71 00:02:57,630 --> 00:03:00,540 tends to be in the millions or billions or trillions 72 00:03:00,540 --> 00:03:03,290 or much, much more for something that's really radioactive. 73 00:03:03,290 --> 00:03:05,040 And it gets annoying writing all the zeros 74 00:03:05,040 --> 00:03:07,130 or all the scientific notation. 75 00:03:07,130 --> 00:03:10,470 And so last time we looked at a simple situation-- 76 00:03:10,470 --> 00:03:13,800 let's say you have some isotope N1 which 77 00:03:13,800 --> 00:03:16,620 decays with the k constant lambda 1 78 00:03:16,620 --> 00:03:23,970 to isotope N2, which decays with the k constant lambda 2 and N3. 79 00:03:23,970 --> 00:03:26,130 And we decided to set up our equations 80 00:03:26,130 --> 00:03:29,040 in the form of change. 81 00:03:29,040 --> 00:03:32,220 Everyone is just a change equals a production 82 00:03:32,220 --> 00:03:38,130 minus a destruction for all cases. 83 00:03:38,130 --> 00:03:40,240 So let's forget the activation part. 84 00:03:40,240 --> 00:03:42,240 For now, we're just going to assume that we have 85 00:03:42,240 --> 00:03:45,060 some amount of isotope, N1. 86 00:03:45,060 --> 00:03:50,790 We'll say we have N1 0 at t equals 0. 87 00:03:50,790 --> 00:03:53,910 And it decays to N2 and decays N3. 88 00:03:53,910 --> 00:03:55,830 So what are the differential equations 89 00:03:55,830 --> 00:04:00,520 describing the rate of change of each of these isotopes? 90 00:04:08,270 --> 00:04:10,825 So how about N1? 91 00:04:10,825 --> 00:04:12,200 Is there any method of production 92 00:04:12,200 --> 00:04:15,220 of isotope N1 in this scenario? 93 00:04:15,220 --> 00:04:17,860 No, we just started off with some N1, 94 00:04:17,860 --> 00:04:22,048 but we do have destruction of N1 via radioactive decay. 95 00:04:22,048 --> 00:04:23,590 And so the amount of changes is going 96 00:04:23,590 --> 00:04:26,230 to be equal to negative the activity. 97 00:04:26,230 --> 00:04:29,800 So for every decay of N1, we lose an N1 atom. 98 00:04:29,800 --> 00:04:33,850 So we just put minus lambda 1 N1. 99 00:04:33,850 --> 00:04:37,810 For every N1 atom that decays, it produces an N2. 100 00:04:37,810 --> 00:04:44,020 So N2 has an equal but different sign production term 101 00:04:44,020 --> 00:04:46,030 and has a similar looking destruction term. 102 00:04:49,470 --> 00:04:54,000 Meanwhile, since N2 becomes N3, then 103 00:04:54,000 --> 00:04:57,103 we just have this simple term right there, 104 00:04:57,103 --> 00:04:58,770 and these are the differential equations 105 00:04:58,770 --> 00:05:01,390 which we want to solve. 106 00:05:01,390 --> 00:05:04,750 We knew from last time that the solution to this equation 107 00:05:04,750 --> 00:05:07,665 is pretty simple. 108 00:05:07,665 --> 00:05:09,540 I'm not going to re-go through the derivation 109 00:05:09,540 --> 00:05:13,290 there since I think that's kind of an easy one. 110 00:05:13,290 --> 00:05:16,355 And N3, we know is pretty simple. 111 00:05:16,355 --> 00:05:17,730 We used the conservation equation 112 00:05:17,730 --> 00:05:21,660 to say that the total amount of all atoms in the system 113 00:05:21,660 --> 00:05:25,830 has to be equal to N10 or N10. 114 00:05:25,830 --> 00:05:31,170 So we know we have N10 equals and N1 plus N2 115 00:05:31,170 --> 00:05:33,930 plus N3 for all time. 116 00:05:33,930 --> 00:05:37,170 So we don't really have to solve for N3 because we can just 117 00:05:37,170 --> 00:05:39,020 deal with it later. 118 00:05:39,020 --> 00:05:40,610 The last thing that we need to derive 119 00:05:40,610 --> 00:05:42,960 is what is the solution to N2. 120 00:05:42,960 --> 00:05:44,570 And I want to correct a mistake that I 121 00:05:44,570 --> 00:05:47,360 made because I'm going to chalk that up to exhaustion 122 00:05:47,360 --> 00:05:49,310 assuming that integrating factor was zero. 123 00:05:49,310 --> 00:05:53,240 It's not zero, so I want to show you why it's not now. 124 00:05:53,240 --> 00:05:55,220 So how do we go about solving this? 125 00:05:55,220 --> 00:05:56,270 What method did we use? 126 00:05:59,360 --> 00:06:01,130 We chose the integration factor method 127 00:06:01,130 --> 00:06:03,080 because it's a nice clean one. 128 00:06:03,080 --> 00:06:06,500 So we rewrite this equation in terms of let's just 129 00:06:06,500 --> 00:06:07,550 say N2 prime-- 130 00:06:11,460 --> 00:06:18,570 I'm sorry-- plus lambda 2 N2 minus lambda 1 N1. 131 00:06:18,570 --> 00:06:22,080 And we don't necessarily want to have an N1 in there 132 00:06:22,080 --> 00:06:24,330 because we want to have one variable only. 133 00:06:24,330 --> 00:06:28,080 So instead of N1, we can substitute this whole thing 134 00:06:28,080 --> 00:06:29,830 in there. 135 00:06:29,830 --> 00:06:36,250 So N10 e to the minus lambda 1t equals zero. 136 00:06:36,250 --> 00:06:39,670 And let's just draw a little thing around here 137 00:06:39,670 --> 00:06:41,710 to help visually separate. 138 00:06:41,710 --> 00:06:45,460 We know how to solve this type of differential equation 139 00:06:45,460 --> 00:06:48,340 because we can define some integrating factor mu 140 00:06:48,340 --> 00:06:52,690 equals e to the minus whatever is in front of the N2. 141 00:06:52,690 --> 00:06:54,460 That's not too hard. 142 00:06:54,460 --> 00:06:57,100 I'm sorry, just e to the integral, not 143 00:06:57,100 --> 00:07:01,870 minus, of lambda 2 dt. 144 00:07:01,870 --> 00:07:05,610 We're just equal to just e lambda 2t. 145 00:07:05,610 --> 00:07:08,290 And we multiply every term in this equation 146 00:07:08,290 --> 00:07:12,760 by mu because we're going to make sure that the stuff here-- 147 00:07:12,760 --> 00:07:16,840 after we multiply by mu and mu and nu 148 00:07:16,840 --> 00:07:19,900 and mu for completeness-- 149 00:07:19,900 --> 00:07:22,060 that stuff in here should be something that looks 150 00:07:22,060 --> 00:07:23,470 like the end of a product rule. 151 00:07:27,273 --> 00:07:28,690 So if we multiply that through, we 152 00:07:28,690 --> 00:07:35,350 get N2 prime e to the lambda 2t plus, 153 00:07:35,350 --> 00:07:39,670 let's see, mu times lambda 2 e to the lambda 154 00:07:39,670 --> 00:07:49,360 2t times n2 minus e to the lambda 2t lambda 1 n10 155 00:07:49,360 --> 00:07:54,640 e to the minus lambda 1t equals zero. 156 00:07:54,640 --> 00:07:57,670 And indeed, we've got right here what 157 00:07:57,670 --> 00:08:00,430 looks like the end result of the product rule 158 00:08:00,430 --> 00:08:03,610 where we have something, let's say, one function times 159 00:08:03,610 --> 00:08:06,130 the derivative of another plus the derivative 160 00:08:06,130 --> 00:08:09,310 of that function times the original other function. 161 00:08:12,390 --> 00:08:17,720 So to compact that up, we can call that, let's say, N2 162 00:08:17,720 --> 00:08:20,780 e to the lambda t-- 163 00:08:20,780 --> 00:08:25,980 sorry, lambda 2t prime minus-- 164 00:08:25,980 --> 00:08:30,920 and I'm going to combine these two exponents right here. 165 00:08:30,920 --> 00:08:39,950 So we'll have minus lambda 1 and 10e to the-- 166 00:08:39,950 --> 00:08:49,400 let's see, is it lambda 2 minus lambda 1t equals zero. 167 00:08:49,400 --> 00:08:51,920 Just going to take this term to the other side 168 00:08:51,920 --> 00:08:57,625 of the equals sign, so I'll just do that, integrate both sides. 169 00:09:01,200 --> 00:09:09,550 And we get N2 e to the lambda 2t equals-- 170 00:09:09,550 --> 00:09:17,920 let's see, that'll be lambda 1 N10 over lambda 2 minus lambda 171 00:09:17,920 --> 00:09:20,375 1 times all that stuff. 172 00:09:28,050 --> 00:09:31,010 I'm going to divide each side of the equation by-- 173 00:09:31,010 --> 00:09:34,740 I'll use a different color for that intermediate step-- 174 00:09:34,740 --> 00:09:35,850 e to the lambda 2t. 175 00:09:40,760 --> 00:09:43,510 And that cancels these out. 176 00:09:43,510 --> 00:09:46,570 That cancels these out. 177 00:09:46,570 --> 00:09:49,520 And I forgot that integrating factor again, didn't I? 178 00:09:49,520 --> 00:09:54,700 Yeah, so there's going to be a plus C somewhere here. 179 00:09:54,700 --> 00:10:00,360 And we're just going to absorb this e to the lambda 2t 180 00:10:00,360 --> 00:10:02,840 into this integrating constant because it's 181 00:10:02,840 --> 00:10:03,840 an integrating constant. 182 00:10:03,840 --> 00:10:05,280 We haven't defined it yet. 183 00:10:05,280 --> 00:10:08,380 Did someone have a question I thought I saw? 184 00:10:08,380 --> 00:10:14,650 OK, and so now this is where I went wrong last time 185 00:10:14,650 --> 00:10:17,410 because I think I was exhausted and commuted in from Columbus. 186 00:10:17,410 --> 00:10:19,630 I just assumed right away that C equals zero, 187 00:10:19,630 --> 00:10:21,190 but it's not the case. 188 00:10:21,190 --> 00:10:27,010 So if we plug-in the condition at t equals 0-- 189 00:10:27,010 --> 00:10:29,723 and two should equal 0-- 190 00:10:29,723 --> 00:10:30,640 let's see what we get. 191 00:10:35,050 --> 00:10:38,400 That would become a zero. 192 00:10:38,400 --> 00:10:42,270 That t would be a zero, which means that we just 193 00:10:42,270 --> 00:10:48,570 end up with the equation lambda 1 N10 194 00:10:48,570 --> 00:10:53,790 over lambda 2 minus lambda 1 plus c equals 195 00:10:53,790 --> 00:10:57,430 zero so obviously the integration constant 196 00:10:57,430 --> 00:11:01,050 is not like we thought it was. 197 00:11:06,590 --> 00:11:14,590 So then C equals negative that stuff. 198 00:11:19,590 --> 00:11:20,980 That make more sense. 199 00:11:20,980 --> 00:11:23,490 So you guys see why the integrating constants not zero. 200 00:11:23,490 --> 00:11:24,348 So in the end-- 201 00:11:24,348 --> 00:11:26,640 I'm going t5o skip ahead a little of the math because I 202 00:11:26,640 --> 00:11:28,560 want to get into nuclear activation analysis-- 203 00:11:28,560 --> 00:11:33,360 we end up with N2 should equal, let's see, 204 00:11:33,360 --> 00:11:40,760 lambda 1 N10 over lambda 1 minus lambda 1 times-- 205 00:11:40,760 --> 00:11:43,450 did I write that twice? 206 00:11:43,450 --> 00:11:44,180 I think I did-- 207 00:11:48,560 --> 00:11:52,410 times e to the-- 208 00:11:52,410 --> 00:11:55,860 let's see, e to the minus lambda 1t minus e 209 00:11:55,860 --> 00:11:59,780 to the minus lambda 2t. 210 00:11:59,780 --> 00:12:03,910 And so since we know N1, we've found N10. 211 00:12:03,910 --> 00:12:06,640 We know N3 from this conservation equation. 212 00:12:06,640 --> 00:12:08,260 We've now fully determined what is 213 00:12:08,260 --> 00:12:10,780 the concentration of every isotope 214 00:12:10,780 --> 00:12:13,000 in this system for all time. 215 00:12:13,000 --> 00:12:16,150 And because the solution to this is not that intuitive-- 216 00:12:16,150 --> 00:12:18,900 like I can't picture what the function looks like in my head. 217 00:12:18,900 --> 00:12:20,440 I don't know about you guys. 218 00:12:20,440 --> 00:12:21,700 Anyone? 219 00:12:21,700 --> 00:12:22,200 No? 220 00:12:22,200 --> 00:12:24,770 OK, I can't either. 221 00:12:24,770 --> 00:12:28,340 I coded them up in this handy graphing calculator where 222 00:12:28,340 --> 00:12:32,420 you can play around with the eye of the concentration N10, which 223 00:12:32,420 --> 00:12:34,610 is just a multiplier for everything, 224 00:12:34,610 --> 00:12:39,083 and the relative half lives lambda 1 and lambda 2. 225 00:12:39,083 --> 00:12:40,500 And I'll share this with you guys, 226 00:12:40,500 --> 00:12:43,810 so you can actually see generally how this works. 227 00:12:43,810 --> 00:12:47,580 So let's start looking at a couple of cases-- 228 00:12:47,580 --> 00:12:50,560 move this a little over so we can see the axes. 229 00:12:50,560 --> 00:12:53,100 Let's say don't worry about anything before T equals zero. 230 00:12:53,100 --> 00:12:55,360 That's kind of an invalid part of the solution. 231 00:12:55,360 --> 00:12:59,320 So I'll just shrink us over there. 232 00:12:59,320 --> 00:13:01,530 And so I've coded up all three of these equations. 233 00:13:01,530 --> 00:13:04,410 There is the solution to N1 highlighted right there. 234 00:13:04,410 --> 00:13:07,420 That's as you'd expect simple exponential decay. 235 00:13:07,420 --> 00:13:09,660 All N1 knows is that it's decaying 236 00:13:09,660 --> 00:13:13,890 according to its own half life or exponential decay equation. 237 00:13:13,890 --> 00:13:18,970 And two, here in the blue, which expands, of course, 238 00:13:18,970 --> 00:13:21,370 looks a little more complicated. 239 00:13:21,370 --> 00:13:26,280 So what we notice here is that N2 is tied directly 240 00:13:26,280 --> 00:13:30,090 to the slope of N1. 241 00:13:30,090 --> 00:13:32,130 That should follow pretty intuitively 242 00:13:32,130 --> 00:13:34,650 from the differential equations because if you 243 00:13:34,650 --> 00:13:38,520 look at the slope of N2, well, it depends directly 244 00:13:38,520 --> 00:13:40,410 on the value of N1. 245 00:13:40,410 --> 00:13:43,380 For very, very short times, this is 246 00:13:43,380 --> 00:13:46,110 the sort of limiting behavior in the and the graphical guidance. 247 00:13:46,110 --> 00:13:47,943 I want to give you two solve questions like, 248 00:13:47,943 --> 00:13:51,690 what's on the exam or how to do a nuclear activation analysis. 249 00:13:51,690 --> 00:13:54,570 Is everyone comfortable with me hiding this board right here? 250 00:13:54,570 --> 00:13:55,070 OK. 251 00:13:58,110 --> 00:14:03,180 So let's say at time is approximately zero, 252 00:14:03,180 --> 00:14:09,570 we know that there's going to be N1 is going to equal about N10. 253 00:14:09,570 --> 00:14:11,580 What's the value of N2 going to be very, very 254 00:14:11,580 --> 00:14:13,574 close to 2 equals 0? 255 00:14:13,574 --> 00:14:14,460 AUDIENCE: Zero. 256 00:14:14,460 --> 00:14:15,780 MICHAEL SHORT: Zero. 257 00:14:15,780 --> 00:14:19,800 So N2 is going to equal 0. 258 00:14:19,800 --> 00:14:22,080 But what's the slope of N2 going to be? 259 00:14:28,387 --> 00:14:29,970 This is how we can get started solving 260 00:14:29,970 --> 00:14:31,920 these graphically without even knowing 261 00:14:31,920 --> 00:14:32,930 what the real forms are. 262 00:14:35,810 --> 00:14:38,810 So we've already said that at a very short time, 263 00:14:38,810 --> 00:14:40,640 N2 is approximately 0. 264 00:14:40,640 --> 00:14:43,670 So if that's zero, then that whole term 265 00:14:43,670 --> 00:14:46,520 is zero, which means that the slope of N2 266 00:14:46,520 --> 00:14:52,970 is approximately lambda 1 N1, just the activity of N1. 267 00:14:52,970 --> 00:14:55,137 And hopefully, that follows intuitively 268 00:14:55,137 --> 00:14:56,720 because it says for really short times 269 00:14:56,720 --> 00:15:04,820 before you get any buildup, the slope of N1 270 00:15:04,820 --> 00:15:07,520 determines the value of N2. 271 00:15:07,520 --> 00:15:10,460 So if we were to start graphing these-- 272 00:15:10,460 --> 00:15:13,490 let's just start looking at some limiting behavior-- that's t, 273 00:15:13,490 --> 00:15:17,575 and we're going to need some colors for this. 274 00:15:17,575 --> 00:15:19,200 Let's stick with the ones on the board. 275 00:15:19,200 --> 00:15:22,720 Oh, hey, awesome. 276 00:15:22,720 --> 00:15:30,180 Make N1 red, N2 blue, and N3 green. 277 00:15:30,180 --> 00:15:33,240 So let's start drawing some limiting behavior. 278 00:15:33,240 --> 00:15:37,430 So we know that N1 starts here at N10. 279 00:15:37,430 --> 00:15:41,280 And we know it's going to start decaying exponentially. 280 00:15:41,280 --> 00:15:46,200 So the slope here is just going to be 281 00:15:46,200 --> 00:15:51,740 minus lambda 1 and N1, which is going to be 282 00:15:51,740 --> 00:15:56,840 the negative slope of N2-- 283 00:15:56,840 --> 00:15:59,840 looks pretty similar, doesn't it? 284 00:15:59,840 --> 00:16:02,930 So we know N2 for very short times 285 00:16:02,930 --> 00:16:07,720 is going to start growing at the same rate that N1 is shrinking. 286 00:16:14,442 --> 00:16:16,150 So we already know what sort of direction 287 00:16:16,150 --> 00:16:18,428 these curves are starting to go in. 288 00:16:18,428 --> 00:16:18,970 How about N3? 289 00:16:21,740 --> 00:16:24,215 What's the value of N3 for very short times? 290 00:16:28,230 --> 00:16:29,240 Anyone call it out. 291 00:16:36,520 --> 00:16:38,820 Well, we've got kind of a solution right here. 292 00:16:38,820 --> 00:16:43,150 If we know that N2 is about zero for very short times, 293 00:16:43,150 --> 00:16:46,020 what would the value of n' three have to be? 294 00:16:46,020 --> 00:16:48,510 Also zero. 295 00:16:48,510 --> 00:16:50,220 And what about the slope of N3? 296 00:16:55,320 --> 00:16:57,300 Also, about zero. 297 00:16:57,300 --> 00:17:02,510 If there's no N2 built up, then there's nothing to create N3. 298 00:17:02,510 --> 00:17:04,310 So we know that our end three curve is 299 00:17:04,310 --> 00:17:07,910 going to start out pretty flat. 300 00:17:12,390 --> 00:17:15,490 Now how do we find some other limiting behavior? 301 00:17:15,490 --> 00:17:18,270 Let's now take the case-- 302 00:17:18,270 --> 00:17:20,665 let's see, I want to rewrite that a little closer here, 303 00:17:20,665 --> 00:17:21,540 so we have some room. 304 00:17:26,680 --> 00:17:30,110 So that's at t equals about zero. 305 00:17:30,110 --> 00:17:37,340 And at t equals infinity, what sort of limiting behavior 306 00:17:37,340 --> 00:17:40,190 do you think we'll have? 307 00:17:40,190 --> 00:17:44,880 What's the value of N1 going to be at infinite time? 308 00:17:44,880 --> 00:17:48,350 Zero-- it will have all decayed away, 309 00:17:48,350 --> 00:17:50,840 will equal zero at t equals infinity. 310 00:17:50,840 --> 00:17:52,050 How about N2? 311 00:17:52,050 --> 00:17:52,910 AUDIENCE: Zero. 312 00:17:52,910 --> 00:17:54,920 MICHAEL SHORT: Zero. 313 00:17:54,920 --> 00:17:56,205 How about N3? 314 00:17:56,205 --> 00:17:57,540 AUDIENCE: [INAUDIBLE] 315 00:17:57,540 --> 00:18:00,230 MICHAEL SHORT: N10-- correct. 316 00:18:00,230 --> 00:18:03,000 Because of that conservation equation right here. 317 00:18:03,000 --> 00:18:08,450 So we know for limiting cases, N1 one is going to be 0. 318 00:18:08,450 --> 00:18:11,180 N2 is going to be 0. 319 00:18:11,180 --> 00:18:14,900 And N3, it's going to be N0. 320 00:18:14,900 --> 00:18:17,900 So we've now filled in all the four corners of the graph 321 00:18:17,900 --> 00:18:22,025 just intuitively without solving the differential equations. 322 00:18:22,025 --> 00:18:23,900 Now let's start to fill in some middle parts. 323 00:18:26,520 --> 00:18:28,860 What other sorts of things can we 324 00:18:28,860 --> 00:18:33,780 determine, like, for example, where H2 has a maximum? 325 00:18:33,780 --> 00:18:36,720 That shouldn't be too hard. 326 00:18:36,720 --> 00:18:39,300 So let's make another separation here. 327 00:18:39,300 --> 00:18:48,687 So what if we want to find out when does the N2 dt equal 0? 328 00:18:48,687 --> 00:18:49,520 What do we do there? 329 00:18:58,490 --> 00:19:01,430 Anyone have an idea? 330 00:19:01,430 --> 00:19:03,820 Using the equations we have up here. 331 00:19:03,820 --> 00:19:06,497 AUDIENCE: [INAUDIBLE] 332 00:19:06,497 --> 00:19:08,080 MICHAEL SHORT: Yeah, well, we can just 333 00:19:08,080 --> 00:19:09,370 take this equation right here. 334 00:19:09,370 --> 00:19:11,680 We can figure that out in terms of N1. 335 00:19:11,680 --> 00:19:14,200 So if D and 2D equals zero, then we 336 00:19:14,200 --> 00:19:20,560 know that lambda 1 N1 is going to equal lambda 2 N2. 337 00:19:20,560 --> 00:19:23,470 What this says intuitively is that the rate of production 338 00:19:23,470 --> 00:19:28,510 of N2 by decaying on 1 equals the rate of destruction of N2 339 00:19:28,510 --> 00:19:30,190 by its own decay. 340 00:19:30,190 --> 00:19:37,650 So at some point, the N2 is going to have to level off. 341 00:19:37,650 --> 00:19:40,920 When that point is depends on the relative differences 342 00:19:40,920 --> 00:19:42,960 between those half lives. 343 00:19:42,960 --> 00:19:46,290 So we already know if we were to just kind of fill in smoothly 344 00:19:46,290 --> 00:19:48,750 what's going to happen, N2 is probably 345 00:19:48,750 --> 00:19:53,910 going to follow something roughly looking like this. 346 00:19:53,910 --> 00:19:55,620 We already know the solution to N1. 347 00:19:55,620 --> 00:19:58,050 I think we can figure that out graphically. 348 00:19:58,050 --> 00:19:59,535 It's simply exponential decay. 349 00:20:04,340 --> 00:20:07,100 The only trick now is how does N3 shape up? 350 00:20:10,140 --> 00:20:11,320 What do you guys think? 351 00:20:11,320 --> 00:20:13,590 How would we go about graphically 352 00:20:13,590 --> 00:20:17,730 plotting these solutions without solving them? 353 00:20:17,730 --> 00:20:20,820 I don't think yet I've given you the full form. 354 00:20:20,820 --> 00:20:24,190 It's kind of ugly, and I doubt that if you looked at it 355 00:20:24,190 --> 00:20:26,880 you'd be able to tell me exactly what it would do. 356 00:20:26,880 --> 00:20:29,220 So this is just the mathematical expression 357 00:20:29,220 --> 00:20:31,590 of N10 minus N1 minus N2. 358 00:20:34,800 --> 00:20:37,790 So how do we figure out all the stuff about N3? 359 00:20:44,650 --> 00:20:45,150 Yeah. 360 00:20:45,150 --> 00:20:47,340 AUDIENCE: You could just draw a curve 361 00:20:47,340 --> 00:20:50,760 so that you get all three curves and always 362 00:20:50,760 --> 00:20:52,017 add it to the same number. 363 00:20:52,017 --> 00:20:52,850 MICHAEL SHORT: Yeah. 364 00:20:52,850 --> 00:20:54,797 AUDIENCE: [INAUDIBLE] 365 00:20:54,797 --> 00:20:56,880 MICHAEL SHORT: Absolutely, that's totally correct. 366 00:20:56,880 --> 00:21:00,630 Yeah, if you just take N10 minus N1 and N2, 367 00:21:00,630 --> 00:21:02,520 that gives you the value of N3. 368 00:21:02,520 --> 00:21:05,160 That's completely correct. 369 00:21:05,160 --> 00:21:07,410 So you could do that sort of one point at a time 370 00:21:07,410 --> 00:21:11,028 and say, well, maybe around there, maybe around there. 371 00:21:11,028 --> 00:21:12,570 It might take a little while, though. 372 00:21:12,570 --> 00:21:14,570 So I want to think what's another intuitive way? 373 00:21:17,390 --> 00:21:20,070 What would the value or the slope of N3 track-- 374 00:21:20,070 --> 00:21:22,700 what other variable in the system? 375 00:21:22,700 --> 00:21:26,995 Or in other words, how are they directly related? 376 00:21:26,995 --> 00:21:27,998 Yeah. 377 00:21:27,998 --> 00:21:31,407 AUDIENCE: The slope of n2 are they equal? 378 00:21:31,407 --> 00:21:32,240 MICHAEL SHORT: Yeah. 379 00:21:32,240 --> 00:21:34,970 The slope of n3 depends directly on the value 380 00:21:34,970 --> 00:21:37,040 of n2 and nothing else. 381 00:21:37,040 --> 00:21:43,640 So initially, you can see the value of n2 is almost 0, 382 00:21:43,640 --> 00:21:46,790 so the slope of n3 is almost 0. 383 00:21:46,790 --> 00:21:52,610 As the value of n2 picks up, so should the slope of n3 384 00:21:52,610 --> 00:21:55,510 until we reach here. 385 00:21:55,510 --> 00:21:57,112 What happens at that point? 386 00:21:57,112 --> 00:21:59,633 AUDIENCE: N2 decreases. 387 00:21:59,633 --> 00:22:00,425 MICHAEL SHORT: Yep. 388 00:22:00,425 --> 00:22:03,740 The rate of production of n2 decreases because the val-- 389 00:22:03,740 --> 00:22:06,410 I'm sorry-- yeah, the rate of production of n3 390 00:22:06,410 --> 00:22:09,200 decreases because the rate of production of n3 391 00:22:09,200 --> 00:22:12,650 is just dependent directly on the value of n2. 392 00:22:12,650 --> 00:22:15,895 So the maximum slope of n3 has to be 393 00:22:15,895 --> 00:22:17,270 right there at which point it has 394 00:22:17,270 --> 00:22:23,850 to start leveling off and eventually reaching 0. 395 00:22:23,850 --> 00:22:26,670 You're going to see this kind of problem on the homework. 396 00:22:26,670 --> 00:22:29,580 You're going to see this kind of problem on the exam. 397 00:22:29,580 --> 00:22:30,860 I guarantee you. 398 00:22:30,860 --> 00:22:32,990 But it's not going to have this exact form. 399 00:22:32,990 --> 00:22:34,650 But what I'll want you to be able to do 400 00:22:34,650 --> 00:22:36,810 is follow this example. 401 00:22:36,810 --> 00:22:40,140 Let's say I pose you a small set of these first order 402 00:22:40,140 --> 00:22:41,760 differential equations. 403 00:22:41,760 --> 00:22:45,120 Can you use any method that you want-- intuitive, graphical, 404 00:22:45,120 --> 00:22:46,260 mathematical-- 405 00:22:46,260 --> 00:22:50,250 to predict what the values and slopes of these isotopes 406 00:22:50,250 --> 00:22:52,410 are going to be as a function of time? 407 00:22:52,410 --> 00:22:54,600 So in order to get nuclear activation analysis right 408 00:22:54,600 --> 00:22:56,580 you need to be able to do this. 409 00:22:56,580 --> 00:23:02,730 In nuclear activation analysis it's just one twist. 410 00:23:02,730 --> 00:23:04,605 I'm going to move this over to add the twist. 411 00:23:08,350 --> 00:23:13,390 You're also producing isotope n1 with a reaction rate. 412 00:23:17,200 --> 00:23:22,120 By some either isotope and not what you put in the reactor. 413 00:23:22,120 --> 00:23:25,630 So if you want to know what your impurities and naught were 414 00:23:25,630 --> 00:23:28,900 to undergo what's called nuclear activation analysis, 415 00:23:28,900 --> 00:23:31,360 then you can figure out, depending on which one you 416 00:23:31,360 --> 00:23:34,700 count, what they could be. 417 00:23:34,700 --> 00:23:35,740 So this right here. 418 00:23:35,740 --> 00:23:39,823 Let's look at the units of this versus the units of this. 419 00:23:39,823 --> 00:23:41,240 First of all, if we're adding them 420 00:23:41,240 --> 00:23:44,220 together they'd better be in the same units, right? 421 00:23:44,220 --> 00:23:48,060 So we already talked about the units of this decay equation. 422 00:23:48,060 --> 00:23:51,113 It's like number of decays per second. 423 00:23:51,113 --> 00:23:52,530 So this reaction right here better 424 00:23:52,530 --> 00:23:55,770 give us a number of atoms produced per second, 425 00:23:55,770 --> 00:23:58,380 or we're kind of messed up in the units. 426 00:23:58,380 --> 00:24:01,740 So anyone remember what is the units of-- 427 00:24:01,740 --> 00:24:04,680 I'll make a little extra piece right here-- 428 00:24:04,680 --> 00:24:08,640 what's the units of microscopic cross sections or barns? 429 00:24:08,640 --> 00:24:10,190 What is that in some sort of SI unit? 430 00:24:10,190 --> 00:24:13,190 AUDIENCE: Centimeter squared. 431 00:24:13,190 --> 00:24:14,070 MICHAEL SHORT: Yep. 432 00:24:14,070 --> 00:24:16,870 It's like a centimeter squared. 433 00:24:16,870 --> 00:24:18,030 And what about flux? 434 00:24:23,030 --> 00:24:25,940 This one you may not know, but it definitely 435 00:24:25,940 --> 00:24:27,470 depends on the number of neutrons 436 00:24:27,470 --> 00:24:30,022 or the number of particles that are there. 437 00:24:30,022 --> 00:24:32,943 AUDIENCE: Is it barns [INAUDIBLE] 438 00:24:32,943 --> 00:24:33,860 MICHAEL SHORT: Almost. 439 00:24:33,860 --> 00:24:35,930 So the flux describes how many particles 440 00:24:35,930 --> 00:24:38,940 pass through a surface in a given time. 441 00:24:38,940 --> 00:24:41,180 So we have how many particles per unit 442 00:24:41,180 --> 00:24:46,010 surface, per unit time. 443 00:24:46,010 --> 00:24:49,070 Ends up being neutrons per centimeter squared per second. 444 00:24:49,070 --> 00:24:51,770 Just like the flux of photons through a space 445 00:24:51,770 --> 00:24:53,950 or the flux of any particle through anywhere, 446 00:24:53,950 --> 00:24:56,000 it describes how many particles go 447 00:24:56,000 --> 00:24:58,400 through a space in a certain time. 448 00:24:58,400 --> 00:25:02,400 And then there's the number of particles that are there. 449 00:25:02,400 --> 00:25:06,740 If we're going with atoms, it's just atoms. 450 00:25:06,740 --> 00:25:08,660 These are all multiplied together. 451 00:25:08,660 --> 00:25:11,270 The centimeter squared cancel. 452 00:25:11,270 --> 00:25:19,360 And we end up with some sort of a atoms per second produced. 453 00:25:19,360 --> 00:25:21,930 We can put in a little hidden unit in the cross section. 454 00:25:21,930 --> 00:25:27,180 If there is a reaction going on where in goes a neutron 455 00:25:27,180 --> 00:25:31,610 and out goes an atom or something, 456 00:25:31,610 --> 00:25:33,680 that should cancel all things out. 457 00:25:33,680 --> 00:25:35,340 Let's not get into that now. 458 00:25:35,340 --> 00:25:37,340 The whole point is we have the same sort of unit 459 00:25:37,340 --> 00:25:40,190 going on here, which is some number of atoms produced 460 00:25:40,190 --> 00:25:41,610 per second. 461 00:25:41,610 --> 00:25:45,553 Same thing as number of atoms decayed per second. 462 00:25:45,553 --> 00:25:46,970 So it's the production-destruction 463 00:25:46,970 --> 00:25:49,180 equivalent of each other. 464 00:25:49,180 --> 00:25:53,400 So, in that way, we can have a reaction rate that we impose, 465 00:25:53,400 --> 00:25:55,020 something artificial, by sticking 466 00:25:55,020 --> 00:25:58,320 something in the reactor and controlling its power level. 467 00:25:58,320 --> 00:26:00,630 And then follow the decay process 468 00:26:00,630 --> 00:26:03,920 which is a natural radioactivity event. 469 00:26:03,920 --> 00:26:06,890 And this is one of the simplest governing 470 00:26:06,890 --> 00:26:09,740 equations for nuclear activation analysis. 471 00:26:09,740 --> 00:26:12,290 Now, one, I might give this to you on an exam 472 00:26:12,290 --> 00:26:14,870 and say OK now draw the curves for nuclear activation 473 00:26:14,870 --> 00:26:16,030 analysis. 474 00:26:16,030 --> 00:26:18,530 And maybe calculate what's the impurity level if you measure 475 00:26:18,530 --> 00:26:20,110 this many counts of something. 476 00:26:20,110 --> 00:26:22,350 Then you just work backward through the math. 477 00:26:22,350 --> 00:26:24,350 But I want to get you guys thinking conceptually 478 00:26:24,350 --> 00:26:25,880 right now. 479 00:26:25,880 --> 00:26:29,300 What are the real equations for nuclear activation analysis? 480 00:26:34,880 --> 00:26:38,600 Let's just do these in terms of n1, n2, n3. 481 00:26:45,586 --> 00:26:48,490 That's dt, d, and 3dt. 482 00:26:51,525 --> 00:26:52,900 We'll start with the stuff that's 483 00:26:52,900 --> 00:26:56,140 up there minus lambda 1 n1. 484 00:26:56,140 --> 00:27:00,740 Plus some cross section times the flux times some other atom 485 00:27:00,740 --> 00:27:01,240 n0. 486 00:27:03,910 --> 00:27:05,410 What other things are we missing? 487 00:27:05,410 --> 00:27:08,110 Are there any other methods of production or destruction 488 00:27:08,110 --> 00:27:10,270 of isotope n1 that we need to consider? 489 00:27:17,460 --> 00:27:20,300 Well, we've got isotope n1 in a reactor. 490 00:27:20,300 --> 00:27:25,430 It can decay, or it can absorb one of the neutrons nearby. 491 00:27:25,430 --> 00:27:27,830 So how do we write that term-- that destruction term? 492 00:27:31,950 --> 00:27:32,450 Yep. 493 00:27:32,450 --> 00:27:37,116 AUDIENCE: Flux times the absorption cross section 494 00:27:37,116 --> 00:27:38,847 times n0. 495 00:27:38,847 --> 00:27:39,680 MICHAEL SHORT: Yeah. 496 00:27:39,680 --> 00:27:42,440 So let's say that's the absorption of atom 1 times 497 00:27:42,440 --> 00:27:43,722 n what did you say? 498 00:27:43,722 --> 00:27:44,430 AUDIENCE: Naught. 499 00:27:44,430 --> 00:27:48,200 MICHAEL SHORT: And would it be n0 or would it be n1? 500 00:27:48,200 --> 00:27:50,508 If you want to know how quick is n1 being destroyed-- 501 00:27:50,508 --> 00:27:51,050 AUDIENCE: OK. 502 00:27:51,050 --> 00:27:53,280 MICHAEL SHORT: --By absorbing neutrons. 503 00:27:53,280 --> 00:27:57,630 So then let's call this absorption of n0. 504 00:27:57,630 --> 00:27:59,830 And is it a plus or a minus? 505 00:27:59,830 --> 00:28:01,205 If it's a destruction rate. 506 00:28:01,205 --> 00:28:02,080 AUDIENCE: [INAUDIBLE] 507 00:28:02,080 --> 00:28:03,247 MICHAEL SHORT: It's a minus. 508 00:28:03,247 --> 00:28:03,870 Yep. 509 00:28:03,870 --> 00:28:06,270 So what's really going on here is 510 00:28:06,270 --> 00:28:08,430 you've got some precursor isotope, whatever 511 00:28:08,430 --> 00:28:12,810 impurity you want to measure n0, producing n1. 512 00:28:12,810 --> 00:28:16,560 And you're looking at n1's decay signature, like its activity, 513 00:28:16,560 --> 00:28:17,910 to determine how much was there. 514 00:28:17,910 --> 00:28:20,340 But you also have to account for the fact 515 00:28:20,340 --> 00:28:23,550 that isotope n1 can be burned in the reactor. 516 00:28:23,550 --> 00:28:25,020 So this is like producing. 517 00:28:27,750 --> 00:28:29,850 This is decaying. 518 00:28:29,850 --> 00:28:34,630 And this is we'll call it being burned. 519 00:28:34,630 --> 00:28:37,510 This isn't burned in the sense of creating of fuel-- 520 00:28:37,510 --> 00:28:39,660 creating energy by burning fuel-- 521 00:28:39,660 --> 00:28:42,310 but we will refer to this sort of in-- 522 00:28:42,310 --> 00:28:44,710 colloquially too burning-- because we're then 523 00:28:44,710 --> 00:28:48,610 absorbing neutrons by n1 and removing that 524 00:28:48,610 --> 00:28:51,250 from the available decay signature. 525 00:28:51,250 --> 00:28:52,030 How about n2? 526 00:28:52,030 --> 00:28:54,640 How do we modify our equation to account correctly 527 00:28:54,640 --> 00:28:57,610 for the production and destruction of n2? 528 00:29:01,555 --> 00:29:03,180 And by the way this is not in the book, 529 00:29:03,180 --> 00:29:06,434 so I don't expect you to know it off the top of your head. 530 00:29:06,434 --> 00:29:08,588 AUDIENCE: It's the same type of thing, flux. 531 00:29:08,588 --> 00:29:10,630 MICHAEL SHORT: Yep So let's first take every term 532 00:29:10,630 --> 00:29:12,190 that we have up there. 533 00:29:12,190 --> 00:29:17,630 We have lambda 1 n1 minus lambda 2 n2. 534 00:29:17,630 --> 00:29:19,370 And what else do we have to account for? 535 00:29:23,710 --> 00:29:24,340 Yep. 536 00:29:24,340 --> 00:29:25,780 AUDIENCE: N2 also being burnt. 537 00:29:25,780 --> 00:29:26,290 MICHAEL SHORT: That's right. 538 00:29:26,290 --> 00:29:27,940 So n2 is also being burned so we'll 539 00:29:27,940 --> 00:29:35,500 have a minus, a flux times the absorption cross section for n2 540 00:29:35,500 --> 00:29:36,760 times the amount of n2. 541 00:29:39,520 --> 00:29:40,380 How about n3? 542 00:29:40,380 --> 00:29:43,880 We'll start with what we had there. 543 00:29:43,880 --> 00:29:46,760 Lambda 2 n2. 544 00:29:46,760 --> 00:29:49,100 And, just like before, we've got to account 545 00:29:49,100 --> 00:29:51,810 for the burning of n3. 546 00:29:51,810 --> 00:29:55,810 So then we'll have minus flux times the absorption 547 00:29:55,810 --> 00:29:59,530 cross section of 3 times n3. 548 00:29:59,530 --> 00:30:02,830 And these equations hold true only for the time 549 00:30:02,830 --> 00:30:06,030 that your material is in the reactor. 550 00:30:06,030 --> 00:30:10,228 What happens when you take the material out of the reactor? 551 00:30:10,228 --> 00:30:12,180 AUDIENCE: You go right back to zero readings. 552 00:30:12,180 --> 00:30:12,630 MICHAEL SHORT: You do. 553 00:30:12,630 --> 00:30:13,130 Yep. 554 00:30:13,130 --> 00:30:19,075 When you come out of the reactor all of the fluxes go to zero. 555 00:30:19,075 --> 00:30:20,200 And that's the end of that. 556 00:30:22,820 --> 00:30:23,405 Yeah. 557 00:30:23,405 --> 00:30:26,030 AUDIENCE: Why don't you account for the production of n2 and n3 558 00:30:26,030 --> 00:30:30,330 in the burn rate? 559 00:30:30,330 --> 00:30:33,037 MICHAEL SHORT: Ah, so did I necessarily specify-- 560 00:30:33,037 --> 00:30:35,370 the question was why don't we account for the production 561 00:30:35,370 --> 00:30:37,590 of n2 and n3 by the burning. 562 00:30:37,590 --> 00:30:38,835 Right? 563 00:30:38,835 --> 00:30:39,460 AUDIENCE: Yeah. 564 00:30:39,460 --> 00:30:42,610 MICHAEL SHORT: Did we specify that absorbing a neutron 565 00:30:42,610 --> 00:30:44,498 is the way to make n2? 566 00:30:44,498 --> 00:30:45,040 AUDIENCE: No. 567 00:30:45,040 --> 00:30:46,930 MICHAEL SHORT: Oftentimes it's not. 568 00:30:46,930 --> 00:30:51,730 So if you burn n1 by absorbing a neutron, 569 00:30:51,730 --> 00:30:53,780 then you will make another isotope 570 00:30:53,780 --> 00:30:56,890 that has the same proton number and one more neutron. 571 00:30:56,890 --> 00:30:59,680 And it may decay by some other crazy way, or it may be stable. 572 00:30:59,680 --> 00:31:00,790 Who knows. 573 00:31:00,790 --> 00:31:07,090 But by decay-- this could be by beta, positron, alpha, 574 00:31:07,090 --> 00:31:08,362 spontaneous fission-- 575 00:31:08,362 --> 00:31:09,820 not gamma because then you wouldn't 576 00:31:09,820 --> 00:31:12,170 have a different isotope. 577 00:31:12,170 --> 00:31:13,970 But oftentimes you won't have-- 578 00:31:13,970 --> 00:31:17,180 the burning process won't produce the same isotopes 579 00:31:17,180 --> 00:31:18,650 as the decay. 580 00:31:18,650 --> 00:31:21,320 So the situation we looked at on Friday when we said let's 581 00:31:21,320 --> 00:31:22,590 escalate things. 582 00:31:22,590 --> 00:31:24,410 That was a purely hypothetical situation 583 00:31:24,410 --> 00:31:27,220 where isotope n2 could be burned to make n0. 584 00:31:27,220 --> 00:31:30,470 I'm not saying it can't happen, but it's not likely. 585 00:31:30,470 --> 00:31:31,850 But still we can model it. 586 00:31:31,850 --> 00:31:33,595 We can model anything. 587 00:31:33,595 --> 00:31:35,220 That just wasn't a realistic situation. 588 00:31:35,220 --> 00:31:36,540 This is. 589 00:31:36,540 --> 00:31:38,790 This is what you guys are going to have to look at 590 00:31:38,790 --> 00:31:40,470 to understand how much impurities there 591 00:31:40,470 --> 00:31:42,180 are in each of your materials. 592 00:31:46,300 --> 00:31:50,630 So this I would say is the complete description 593 00:31:50,630 --> 00:31:53,535 of nuclear activation analysis in the reactor. 594 00:31:53,535 --> 00:31:55,160 At which point you then have to account 595 00:31:55,160 --> 00:31:58,510 for what happens when you turn the reactor off. 596 00:32:01,882 --> 00:32:02,590 So what actually? 597 00:32:02,590 --> 00:32:04,840 What physically happens when you turn the reactor off? 598 00:32:10,020 --> 00:32:10,520 Yep. 599 00:32:10,520 --> 00:32:11,093 Oh Yeah. 600 00:32:11,093 --> 00:32:12,010 You've answered a lot. 601 00:32:12,010 --> 00:32:12,840 So Chris, yeah. 602 00:32:12,840 --> 00:32:15,946 CHRIS: Well, you try to-- you put your control rods all 603 00:32:15,946 --> 00:32:17,810 the way in and try to stop as many neutrons 604 00:32:17,810 --> 00:32:20,300 as you can to stop the chain reaction. 605 00:32:20,300 --> 00:32:21,460 MICHAEL SHORT: Yep. 606 00:32:21,460 --> 00:32:23,120 So normally to shut down the reactor 607 00:32:23,120 --> 00:32:25,690 you'd put the control rods in and shut down the reactor. 608 00:32:25,690 --> 00:32:28,163 Or the easier thing is just pull the rabbit out. 609 00:32:28,163 --> 00:32:29,830 Remember those little polyethylene tubes 610 00:32:29,830 --> 00:32:31,000 I showed you? 611 00:32:31,000 --> 00:32:34,120 This way we can keep the reactor on and remove your samples 612 00:32:34,120 --> 00:32:35,240 without changing anything. 613 00:32:35,240 --> 00:32:37,630 So it makes the reactor folks-- 614 00:32:37,630 --> 00:32:39,520 angry would be an understatement-- 615 00:32:39,520 --> 00:32:43,660 to constantly change the power level of the reactor. 616 00:32:43,660 --> 00:32:47,120 Reactors, especially power reactors and research reactors, 617 00:32:47,120 --> 00:32:49,270 they're kind of like Mack trucks. 618 00:32:49,270 --> 00:32:51,598 If they're moving they want to stay moving, 619 00:32:51,598 --> 00:32:53,890 and if they're not moving they don't want to be moving. 620 00:32:53,890 --> 00:32:57,040 And it takes an awful lot of effort to change that. 621 00:32:57,040 --> 00:32:59,710 It also happens to screw up experiments. 622 00:32:59,710 --> 00:33:03,550 If you are irradiating something like I was a couple months ago 623 00:33:03,550 --> 00:33:06,340 for 30 days, you want to have a constant flux 624 00:33:06,340 --> 00:33:08,020 so that your calculations are easy. 625 00:33:08,020 --> 00:33:10,810 You don't want 15 students to come in and turn the knobs 626 00:33:10,810 --> 00:33:12,250 all up and down, and then you have 627 00:33:12,250 --> 00:33:14,920 to account for that in your data. 628 00:33:14,920 --> 00:33:16,090 Which has happened. 629 00:33:16,090 --> 00:33:18,640 So you guys are going to be manipulating the reactor 630 00:33:18,640 --> 00:33:22,060 power when the experiments are out, and it's at low power. 631 00:33:22,060 --> 00:33:24,700 So you're won't be infuriating anyone else on campus 632 00:33:24,700 --> 00:33:26,790 like we did last year. 633 00:33:26,790 --> 00:33:29,290 So if you didn't account for that, but they still let us in. 634 00:33:29,290 --> 00:33:30,190 So they're bad. 635 00:33:30,190 --> 00:33:30,870 Whatever. 636 00:33:30,870 --> 00:33:31,570 [LAUGHING] 637 00:33:31,570 --> 00:33:32,350 Yeah. 638 00:33:32,350 --> 00:33:35,050 So after you either shut down the reactor 639 00:33:35,050 --> 00:33:37,750 or pull the rabbit out of the reactor then 640 00:33:37,750 --> 00:33:40,390 the production and destruction by neutrons is over 641 00:33:40,390 --> 00:33:42,460 but the decay keeps going. 642 00:33:42,460 --> 00:33:44,890 Which means if you wait too long, like for some 643 00:33:44,890 --> 00:33:48,170 of those short isotopes, if you wait more than a day or so, 644 00:33:48,170 --> 00:33:50,080 you'll have so little activity left 645 00:33:50,080 --> 00:33:52,160 that you won't be able to measure it. 646 00:33:52,160 --> 00:33:54,880 So what we're going to be doing is sticking your samples 647 00:33:54,880 --> 00:33:57,730 into the reactor for maybe an hour or so, 648 00:33:57,730 --> 00:33:59,920 pulling them out, and immediately running them over 649 00:33:59,920 --> 00:34:03,498 to the detector, so that we get the most signal per unit time. 650 00:34:03,498 --> 00:34:06,040 Because the things are going to be the hottest when they come 651 00:34:06,040 --> 00:34:09,219 right out of the reactor, and every second you lose 652 00:34:09,219 --> 00:34:11,020 from there you lose signal. 653 00:34:11,020 --> 00:34:13,090 Which means you have to account for longer 654 00:34:13,090 --> 00:34:14,980 to get the same amount of information 655 00:34:14,980 --> 00:34:16,397 with the same certainty. 656 00:34:16,397 --> 00:34:17,980 This is a nice segue way to what we'll 657 00:34:17,980 --> 00:34:21,130 be talking about Thursday which is statistics, certainty, 658 00:34:21,130 --> 00:34:22,270 and precision. 659 00:34:22,270 --> 00:34:24,639 How long do you have to count something 660 00:34:24,639 --> 00:34:27,760 to be confident within some interval 661 00:34:27,760 --> 00:34:30,000 that you've got the correct activity? 662 00:34:30,000 --> 00:34:34,730 For background counts-- who here is made a NSC Geiger counter? 663 00:34:34,730 --> 00:34:36,080 Hopefully almost all of you. 664 00:34:36,080 --> 00:34:37,580 Maybe you guys remember how long you 665 00:34:37,580 --> 00:34:40,980 had to count to be 95% sure that your background rate was 666 00:34:40,980 --> 00:34:42,870 accurate. 667 00:34:42,870 --> 00:34:46,510 It ends up being about 67 minutes or over an hour, 668 00:34:46,510 --> 00:34:49,040 and the reason is because the count rate is very low. 669 00:34:49,040 --> 00:34:51,460 So I'll do a little flash forward to Thursday 670 00:34:51,460 --> 00:34:53,380 since we're talking about it. 671 00:34:53,380 --> 00:34:56,080 When you count something with a very low count rate, 672 00:34:56,080 --> 00:34:58,750 you have to account for longer to be as confident 673 00:34:58,750 --> 00:35:00,470 that your number is correct. 674 00:35:00,470 --> 00:35:03,460 So let's say you want to be 95% confident 675 00:35:03,460 --> 00:35:07,120 or within plus or minus 2 standard deviations or 2 sigma. 676 00:35:07,120 --> 00:35:09,340 You have to count for longer and longer. 677 00:35:09,340 --> 00:35:10,990 For something that's really radioactive 678 00:35:10,990 --> 00:35:14,590 you can be sure, or 95% sure, that the count 679 00:35:14,590 --> 00:35:18,010 rate you measured is accurate for a shorter counting time. 680 00:35:18,010 --> 00:35:20,480 So everything in this class seems to come up in trade-offs. 681 00:35:20,480 --> 00:35:20,980 Right? 682 00:35:20,980 --> 00:35:23,530 You trade off stability for a half-life. 683 00:35:23,530 --> 00:35:26,200 You trade off decay constant for half-life. 684 00:35:26,200 --> 00:35:29,220 You trade off binding energy for excess mass. 685 00:35:29,220 --> 00:35:32,880 You trade off counting time and precision. 686 00:35:32,880 --> 00:35:34,830 You trade off exposure and dose. which 687 00:35:34,830 --> 00:35:36,550 you're going to get into later. 688 00:35:36,550 --> 00:35:38,710 We'll see if anyone wants to use a cell phone 689 00:35:38,710 --> 00:35:40,690 or eat irradiated food afterwards. 690 00:35:40,690 --> 00:35:44,470 And I do all the time, so that should tell you the answer. 691 00:35:44,470 --> 00:35:47,172 So in the last seven minutes or so, 692 00:35:47,172 --> 00:35:48,880 I want to walk you through playing around 693 00:35:48,880 --> 00:35:51,670 with what happens when you change the values of lambda 694 00:35:51,670 --> 00:35:53,710 1 and lambda 2? 695 00:35:53,710 --> 00:35:57,010 So what do they look like when the half-lives are 696 00:35:57,010 --> 00:36:01,160 roughly equal and when one is much larger than the other one? 697 00:36:01,160 --> 00:36:03,010 So let's set them to be about equal. 698 00:36:03,010 --> 00:36:04,270 These are just unitless. 699 00:36:04,270 --> 00:36:06,670 So let's set them equal to one. 700 00:36:06,670 --> 00:36:10,750 I think the system explodes when we set them exactly equal 701 00:36:10,750 --> 00:36:14,700 because that term right there. 702 00:36:14,700 --> 00:36:18,250 So let's say that's 1.001. 703 00:36:18,250 --> 00:36:20,500 It's about as close as we can get, 704 00:36:20,500 --> 00:36:23,610 and let's confirm that we get the same sort of behavior. 705 00:36:23,610 --> 00:36:26,910 So isotope n1 just follows exponential decay. 706 00:36:26,910 --> 00:36:28,890 There's nothing that changes that. 707 00:36:28,890 --> 00:36:34,710 Isotope 2, its slope tracks the value of isotope 1 708 00:36:34,710 --> 00:36:37,920 for a little while until you build up enough n2 709 00:36:37,920 --> 00:36:39,690 that it starts to decay. 710 00:36:39,690 --> 00:36:42,270 You can find when that point is when 711 00:36:42,270 --> 00:36:46,470 lambda 1 n1 equals lambda 2 n2. 712 00:36:46,470 --> 00:36:48,930 There's one little step that we didn't fill in if you 713 00:36:48,930 --> 00:36:51,148 want to find the value of n2. 714 00:36:51,148 --> 00:36:53,190 So then you can just rearrange this a little bit, 715 00:36:53,190 --> 00:36:56,100 and you'll say n2 would have to equal lambda 716 00:36:56,100 --> 00:37:00,940 1 over lambda 2 times n1. 717 00:37:00,940 --> 00:37:06,960 Which is n1 0 e to the minus lambda 1 t. 718 00:37:06,960 --> 00:37:11,400 So if you want to find that point right there in time, 719 00:37:11,400 --> 00:37:14,730 you can solve this. 720 00:37:14,730 --> 00:37:17,130 Then let's look at n3. 721 00:37:17,130 --> 00:37:22,440 So n3 when n2 is almost 0, n3 slope is almost 0. 722 00:37:22,440 --> 00:37:24,555 It's a little hard to see because-- 723 00:37:24,555 --> 00:37:27,180 I'll tell you what-- let's make all the half lives longer which 724 00:37:27,180 --> 00:37:29,640 kind of expands the graph. 725 00:37:29,640 --> 00:37:30,390 Wrong way. 726 00:37:33,890 --> 00:37:35,492 Let's make it-- 727 00:37:35,492 --> 00:37:42,650 Ah, we'll just move that decimal point 0.1. 728 00:37:42,650 --> 00:37:43,357 There we go. 729 00:37:43,357 --> 00:37:44,690 That's like expanding the graph. 730 00:37:44,690 --> 00:37:45,190 Right? 731 00:37:45,190 --> 00:37:50,120 So when n2 is almost 0, the slope of n3 is almost 0. 732 00:37:50,120 --> 00:37:55,100 And when n2 reaches a maximum, so does the slope of n3. 733 00:37:55,100 --> 00:38:02,090 Just like we predicted using our graphical method right here. 734 00:38:02,090 --> 00:38:03,440 And then over longer times-- 735 00:38:03,440 --> 00:38:05,870 let's put the half lives back to the way they were. 736 00:38:09,210 --> 00:38:13,778 Over long times n3 trends to n1 0. 737 00:38:13,778 --> 00:38:15,320 Don't let that little piece fool you. 738 00:38:15,320 --> 00:38:19,120 Again t equals less than 0 is not a valid time for this, 739 00:38:19,120 --> 00:38:20,780 so we're not accounting for that. 740 00:38:20,780 --> 00:38:25,790 And n3 tracks right to here to the value of n1 0, 741 00:38:25,790 --> 00:38:28,250 and n2 and n3 turn to 0. 742 00:38:28,250 --> 00:38:31,700 So for this case where you have the half-lives roughly 743 00:38:31,700 --> 00:38:35,770 equal to each other, you can expect a pretty big bump in n2. 744 00:38:35,770 --> 00:38:40,750 What's going to happen when lambda 1 is extraordinarily 745 00:38:40,750 --> 00:38:45,026 big meaning the half-life of n1 is extraordinarily short. 746 00:38:45,026 --> 00:38:46,484 What do you guys think will happen? 747 00:38:51,790 --> 00:38:55,350 Not mathematically but physically. 748 00:38:55,350 --> 00:38:59,624 If n1 just kind of goes ba-boom and instantly decays away. 749 00:38:59,624 --> 00:39:02,155 AUDIENCE: There would be a lot of n2-- 750 00:39:02,155 --> 00:39:02,655 right then. 751 00:39:02,655 --> 00:39:03,447 MICHAEL SHORT: Yep. 752 00:39:03,447 --> 00:39:04,322 AUDIENCE: [INAUDIBLE] 753 00:39:04,322 --> 00:39:05,822 MICHAEL SHORT: Your n1 is just going 754 00:39:05,822 --> 00:39:07,560 to turn into n2 right away, and n2 755 00:39:07,560 --> 00:39:10,800 is going to take its sweet time decaying to n3. 756 00:39:10,800 --> 00:39:13,140 So let's see what that looks like. 757 00:39:13,140 --> 00:39:20,190 If lambda 2 is much bigger than lambda 1, 758 00:39:20,190 --> 00:39:23,860 let's make the maxima a little different. 759 00:39:23,860 --> 00:39:27,580 Change our slider value a bit. 760 00:39:27,580 --> 00:39:34,430 So if l2 is big and l1 is small, well, 761 00:39:34,430 --> 00:39:37,980 let me change the actual axes to make 762 00:39:37,980 --> 00:39:40,630 this a little easier to see. 763 00:39:40,630 --> 00:39:42,780 There we go. 764 00:39:42,780 --> 00:39:45,020 You can see that much, much more quickly 765 00:39:45,020 --> 00:39:48,470 than we have it in this graph right here l1 just decays away 766 00:39:48,470 --> 00:39:49,670 right away. 767 00:39:49,670 --> 00:39:51,640 L-- I'm sorry-- n1 decays right away. 768 00:39:51,640 --> 00:39:55,640 n2 builds up to a much higher relative value 769 00:39:55,640 --> 00:39:58,940 because it's produced faster than it's destroyed 770 00:39:58,940 --> 00:40:00,620 for short amounts of time. 771 00:40:00,620 --> 00:40:03,710 So you can end up with a great spike in n2 772 00:40:03,710 --> 00:40:08,500 which slowly decays away to n3. 773 00:40:08,500 --> 00:40:10,180 How about the opposite effect? 774 00:40:10,180 --> 00:40:14,410 What if l1 lambda 1 is really, really small 775 00:40:14,410 --> 00:40:17,080 indicating a very long half-life, 776 00:40:17,080 --> 00:40:19,450 and lambda 2 is really, really large 777 00:40:19,450 --> 00:40:22,260 indicating a small half-life. 778 00:40:22,260 --> 00:40:22,760 Yeah. 779 00:40:22,760 --> 00:40:25,180 AUDIENCE: It would basically go from n1 to n3. 780 00:40:25,180 --> 00:40:27,833 As soon as it goes to n2, it's going to decay to n3. 781 00:40:27,833 --> 00:40:29,000 MICHAEL SHORT: That's right. 782 00:40:29,000 --> 00:40:31,010 In this case you've got n2 as soon 783 00:40:31,010 --> 00:40:33,493 as its created self-destructs. 784 00:40:33,493 --> 00:40:34,910 So let's see what that looks like. 785 00:40:34,910 --> 00:40:41,010 So we can just slide l2 to be big, slide l1 to be small, 786 00:40:41,010 --> 00:40:46,270 and you can actually graphically see n2 just shrink 787 00:40:46,270 --> 00:40:48,030 towards the x-axis. 788 00:40:48,030 --> 00:40:50,980 And it's almost like you only have two equations. 789 00:40:50,980 --> 00:40:52,720 It's like you just have n1 and n3 790 00:40:52,720 --> 00:40:55,150 and n2 basically doesn't exist. 791 00:40:55,150 --> 00:40:57,850 Where the slope of-- 792 00:40:57,850 --> 00:41:01,990 where the slope of n3, except at extremely short times, 793 00:41:01,990 --> 00:41:04,598 just tracks the value of n1. 794 00:41:04,598 --> 00:41:06,140 And I know in the book they're called 795 00:41:06,140 --> 00:41:08,120 secular or transient equilbria. 796 00:41:08,120 --> 00:41:11,045 I'm not going to require that you memorize those terms. 797 00:41:11,045 --> 00:41:12,920 It's more important to me that I can give you 798 00:41:12,920 --> 00:41:14,600 a real physical situation. 799 00:41:14,600 --> 00:41:17,470 Say here's these three isotopes, for four isotopes, 800 00:41:17,470 --> 00:41:20,690 or six doesn't matter because we can solve these pretty quickly. 801 00:41:20,690 --> 00:41:22,190 Tell me what's going to happen based 802 00:41:22,190 --> 00:41:25,070 on the relative half-lives as long as they 803 00:41:25,070 --> 00:41:26,960 decay in a nice linear chain. 804 00:41:26,960 --> 00:41:28,850 I'm not going to give you something where 805 00:41:28,850 --> 00:41:31,760 n1 can beget n1 or n4 or n6. 806 00:41:31,760 --> 00:41:35,360 Because at that point you can construct the equations, 807 00:41:35,360 --> 00:41:39,450 but I don't expect you to be able to graphically solve them. 808 00:41:39,450 --> 00:41:42,450 And I may also throw you curveballs 809 00:41:42,450 --> 00:41:44,910 like nuclear activation analysis to see well 810 00:41:44,910 --> 00:41:48,640 what happens when you turn on or turn off a reactor. 811 00:41:48,640 --> 00:41:50,300 I've got an example of that too. 812 00:41:55,000 --> 00:41:59,680 We're right at this point here, I guess, t equals 50. 813 00:41:59,680 --> 00:42:00,190 Yeah. 814 00:42:00,190 --> 00:42:03,340 I've set it up such that you turn off the reactor 815 00:42:03,340 --> 00:42:07,120 and n3 is stable right there, but n1 and n2 816 00:42:07,120 --> 00:42:09,020 continue to decay. 817 00:42:09,020 --> 00:42:10,920 So it's not hard to cad these-- 818 00:42:10,920 --> 00:42:12,582 to code these sorts of things up. 819 00:42:12,582 --> 00:42:14,290 I'll share the links with these equations 820 00:42:14,290 --> 00:42:16,570 so you guys can play with them yourselves. 821 00:42:16,570 --> 00:42:19,960 Add to them yourselves, and try just getting an intuitive feel 822 00:42:19,960 --> 00:42:23,052 for how series radioactive decay happens. 823 00:42:23,052 --> 00:42:25,510 So I want to know now that we spent a couple of days on it, 824 00:42:25,510 --> 00:42:28,420 would you guys be comfortable setting up 825 00:42:28,420 --> 00:42:30,310 sets of differential equations like this? 826 00:42:30,310 --> 00:42:33,090 Say yes, no, maybe? 827 00:42:33,090 --> 00:42:34,970 I see a lot of up and down shaking heads. 828 00:42:34,970 --> 00:42:36,813 That's a promising sign. 829 00:42:36,813 --> 00:42:38,980 If not I'm willing to spend a little more time on it 830 00:42:38,980 --> 00:42:40,980 on Thursday if folks would like a bit of review. 831 00:42:42,918 --> 00:42:44,460 And if you're afraid to tell me, just 832 00:42:44,460 --> 00:42:46,110 send me an email anonymous or not. 833 00:42:46,110 --> 00:42:46,373 Yeah? 834 00:42:46,373 --> 00:42:48,040 AUDIENCE: Do you think maybe Thursday we 835 00:42:48,040 --> 00:42:50,820 could do a like a real example? 836 00:42:50,820 --> 00:42:51,720 MICHAEL SHORT: Yeah. 837 00:42:51,720 --> 00:42:53,697 AUDIENCE: Of a like a series. 838 00:42:53,697 --> 00:42:54,780 MICHAEL SHORT: I think so. 839 00:42:54,780 --> 00:42:57,035 Yeah, with real example with numbers and everything. 840 00:42:57,035 --> 00:42:57,660 AUDIENCE: Yeah. 841 00:42:57,660 --> 00:42:58,493 MICHAEL SHORT: Sure. 842 00:42:58,493 --> 00:42:59,640 OK. 843 00:42:59,640 --> 00:43:02,250 Well, we can make one of those up for Thursday. 844 00:43:02,250 --> 00:43:03,930 Cool. 845 00:43:03,930 --> 00:43:06,060 And what about the graphical solution 846 00:43:06,060 --> 00:43:10,740 method since I don't know whether they teach that 847 00:43:10,740 --> 00:43:13,230 in the GIRs, but what I do want to be able to do 848 00:43:13,230 --> 00:43:14,670 is look at the limiting cases. 849 00:43:14,670 --> 00:43:17,430 In other words, fill in the four corners of the graph. 850 00:43:17,430 --> 00:43:20,790 At t equals 0, what are things actually doing? 851 00:43:20,790 --> 00:43:23,440 n1 is just decaying at its half-life. 852 00:43:23,440 --> 00:43:25,270 There is no n2 yet. 853 00:43:25,270 --> 00:43:27,440 So these slopes are equal and opposite. 854 00:43:27,440 --> 00:43:31,260 And there's no n3 yet, so that there is no slope of n3. 855 00:43:31,260 --> 00:43:35,158 So I would like you guys to try reproducing this. 856 00:43:35,158 --> 00:43:37,700 And I will-- again I'll provide pictures of these blackboards 857 00:43:37,700 --> 00:43:39,120 so you guys can see, but it would 858 00:43:39,120 --> 00:43:41,850 be very helpful for you guys to try to reproduce these graphs 859 00:43:41,850 --> 00:43:43,200 as we saw them. 860 00:43:43,200 --> 00:43:46,160 Then you can check them here on the graphical calculator, 861 00:43:46,160 --> 00:43:49,250 and then play around with the amount of n0, or-- 862 00:43:49,250 --> 00:43:50,820 I think I just broke it. 863 00:43:50,820 --> 00:43:52,930 Let's just call that one. 864 00:43:52,930 --> 00:43:54,250 There we go. 865 00:43:54,250 --> 00:43:59,830 And play around with sliders or values of n1, n2, or n3. 866 00:43:59,830 --> 00:44:02,530 That's an interesting solution. 867 00:44:02,530 --> 00:44:04,440 So since it's about four or five of, 868 00:44:04,440 --> 00:44:07,310 I want to open it up to any questions you guys may have. 869 00:44:07,310 --> 00:44:07,826 Yeah. 870 00:44:07,826 --> 00:44:10,350 AUDIENCE: I have a question from the [INAUDIBLE] First 871 00:44:10,350 --> 00:44:11,015 time do this. 872 00:44:11,015 --> 00:44:14,360 Did you have-- do you know what integrated video because 873 00:44:14,360 --> 00:44:16,620 like there are endless possibilities if you 874 00:44:16,620 --> 00:44:18,840 just [INAUDIBLE] add up to the right mass number? 875 00:44:18,840 --> 00:44:20,443 MICHAEL SHORT: Oh yeah. 876 00:44:20,443 --> 00:44:22,110 The questions for a spontaneous fission. 877 00:44:22,110 --> 00:44:24,700 What fission products do you choose? 878 00:44:24,700 --> 00:44:26,790 I'll say they're all good. 879 00:44:26,790 --> 00:44:31,270 As long as you pick something with roughly equalish masses, 880 00:44:31,270 --> 00:44:33,900 so you don't pick like it fizzes into hydrogen and something 881 00:44:33,900 --> 00:44:35,790 quite smaller, which should be better known 882 00:44:35,790 --> 00:44:37,350 as just proton emission. 883 00:44:37,350 --> 00:44:40,090 You're going to get roughly the same answer. 884 00:44:40,090 --> 00:44:40,810 Yep. 885 00:44:40,810 --> 00:44:43,500 AUDIENCE: Would that be something we just like set up. 886 00:44:43,500 --> 00:44:44,950 Like the top number is 80. 887 00:44:44,950 --> 00:44:50,750 We just look at whatever 40, 42, 38 arms pick a number. 888 00:44:50,750 --> 00:44:53,340 MICHAEL SHORT: Roll a D 80. 889 00:44:53,340 --> 00:44:56,920 You'll get basically the same result. Roll an 80 sided dice. 890 00:44:56,920 --> 00:45:00,540 Hopefully at MIT you could find one, or write a program 891 00:45:00,540 --> 00:45:05,220 to make random number between about 10 and 80 or 10 and 70. 892 00:45:05,220 --> 00:45:09,930 Let's go to the actual problem set to see what you guys mean. 893 00:45:09,930 --> 00:45:13,570 I want to make sure I'm answering the correct question. 894 00:45:13,570 --> 00:45:17,541 Problem statement Yep. 895 00:45:17,541 --> 00:45:19,896 Yep. 896 00:45:19,896 --> 00:45:21,900 So allowable this is for this one 897 00:45:21,900 --> 00:45:23,280 allowable nuclear reactions. 898 00:45:23,280 --> 00:45:24,030 Yep. 899 00:45:24,030 --> 00:45:26,370 So for a spontaneous fission just pick one 900 00:45:26,370 --> 00:45:28,470 you think would be likely. 901 00:45:28,470 --> 00:45:30,450 You can also look up what sort of isotopes 902 00:45:30,450 --> 00:45:32,393 are created when elements fizz. 903 00:45:32,393 --> 00:45:33,810 It's not straight down the middle, 904 00:45:33,810 --> 00:45:36,300 so like uranium won't often split into two 905 00:45:36,300 --> 00:45:38,340 equally sized fission products. 906 00:45:38,340 --> 00:45:40,410 They'll have roughly different masses, 907 00:45:40,410 --> 00:45:42,143 but which ones you pick? 908 00:45:42,143 --> 00:45:44,310 You're still going to get the same general solution. 909 00:45:44,310 --> 00:45:45,310 Yep. 910 00:45:45,310 --> 00:45:47,390 AUDIENCE: I'm so confused on how to find one. 911 00:45:47,390 --> 00:45:50,954 Like a situation where it is unlikely possible because is 912 00:45:50,954 --> 00:45:55,360 it spontaneous fission or is it generally possible for heavier 913 00:45:55,360 --> 00:45:57,798 elements like transuranic elements? 914 00:45:57,798 --> 00:46:00,340 MICHAEL SHORT: So the question is when is spontaneous fission 915 00:46:00,340 --> 00:46:00,860 possible? 916 00:46:00,860 --> 00:46:03,280 Is it only for heavy elements? 917 00:46:03,280 --> 00:46:05,380 There is a difference between energetically 918 00:46:05,380 --> 00:46:08,500 possible and observed. 919 00:46:08,500 --> 00:46:11,140 That's part of the trick to this problem. 920 00:46:11,140 --> 00:46:14,350 If you do out the Q equation to find out for add fission 921 00:46:14,350 --> 00:46:20,593 products that you picked, you may be surprised at the result. 922 00:46:20,593 --> 00:46:21,510 However, you're right. 923 00:46:21,510 --> 00:46:24,390 You don't tend to see spontaneous fission happen 924 00:46:24,390 --> 00:46:27,670 until you get to really heavy things like uranium. 925 00:46:27,670 --> 00:46:31,050 So there's more to will something spontaneously fizz 926 00:46:31,050 --> 00:46:35,450 than does the Q value allow it to happen. 927 00:46:35,450 --> 00:46:36,950 So I don't want to give away anymore 928 00:46:36,950 --> 00:46:40,140 but I will say if you're surprised at your result, 929 00:46:40,140 --> 00:46:42,710 you might be right. 930 00:46:42,710 --> 00:46:43,430 Yep. 931 00:46:43,430 --> 00:46:47,210 AUDIENCE: On this question for electron capture. 932 00:46:47,210 --> 00:46:48,710 In the equation you gave us, you're 933 00:46:48,710 --> 00:46:50,670 calculating Q in an electronic capture. 934 00:46:50,670 --> 00:46:56,210 Its the massive parents minus the dollars minus the I 935 00:46:56,210 --> 00:47:00,056 think binding energy of the electrons is what you wanted. 936 00:47:00,056 --> 00:47:02,960 When I try find out what the binding energy of an electron 937 00:47:02,960 --> 00:47:05,005 is, it says it depends on the shell that its in. 938 00:47:05,005 --> 00:47:06,260 MICHAEL SHORT: Yep. 939 00:47:06,260 --> 00:47:08,970 AUDIENCE: So how do we know which 940 00:47:08,970 --> 00:47:11,285 electron the nucleus is after? 941 00:47:11,285 --> 00:47:14,400 Do we assume its from the innermost shell? 942 00:47:14,400 --> 00:47:15,350 MICHAEL SHORT: Yep. 943 00:47:15,350 --> 00:47:17,900 So the question was if you're doing electron capture where 944 00:47:17,900 --> 00:47:20,090 you have some parent nucleus and you've 945 00:47:20,090 --> 00:47:23,990 got a lot of electron shells. 946 00:47:23,990 --> 00:47:26,450 The binding energy of every electron is different. 947 00:47:26,450 --> 00:47:28,440 Which one goes in? 948 00:47:28,440 --> 00:47:30,960 One, you find the data on the nest tables. 949 00:47:30,960 --> 00:47:34,980 Two, chances are it will be the closest one. 950 00:47:34,980 --> 00:47:37,650 So a roughly 80% of the time these things 951 00:47:37,650 --> 00:47:41,310 happen from the K shell with very decreasing probabilities 952 00:47:41,310 --> 00:47:42,390 from the outer shells. 953 00:47:42,390 --> 00:47:46,010 So you can pick either the k or the L shell, 954 00:47:46,010 --> 00:47:48,030 like both things may happen. 955 00:47:48,030 --> 00:47:51,030 But I would say for simplicity's sake assume it's an inner most 956 00:47:51,030 --> 00:47:52,255 shell electron. 957 00:47:52,255 --> 00:47:54,630 And you can look up the binding energy on the NIST tables 958 00:47:54,630 --> 00:47:55,797 on the learning module site. 959 00:47:58,890 --> 00:47:59,920 So any other questions? 960 00:47:59,920 --> 00:48:01,120 Yeah, Luke. 961 00:48:01,120 --> 00:48:05,840 LUKE: On graphing the spectrum, the satellite 962 00:48:05,840 --> 00:48:10,000 intensity vs. the energy for 4 2. 963 00:48:10,000 --> 00:48:11,890 MICHAEL SHORT: For 4 2. 964 00:48:11,890 --> 00:48:12,520 Ah yes. 965 00:48:12,520 --> 00:48:14,530 So graphing the-- this would be like 966 00:48:14,530 --> 00:48:16,360 if you had an electron detector. 967 00:48:16,360 --> 00:48:18,290 Is that what I asked for? 968 00:48:18,290 --> 00:48:20,420 4 2, write the full nuclear reactions 969 00:48:20,420 --> 00:48:23,660 and draw the energy spectrum you expect from each released form 970 00:48:23,660 --> 00:48:27,140 of radiation including secondary ejections of particles 971 00:48:27,140 --> 00:48:28,410 or photons. 972 00:48:28,410 --> 00:48:33,522 So by a spectrum, I mean, yep, energy versus intensity. 973 00:48:33,522 --> 00:48:34,490 LUKE: OK. 974 00:48:34,490 --> 00:48:35,948 MICHAEL SHORT: So there you'll have 975 00:48:35,948 --> 00:48:38,660 to account for the spectrum like the various range 976 00:48:38,660 --> 00:48:40,490 of the betas that can be released, 977 00:48:40,490 --> 00:48:45,560 any ejected electrons, any Auger electrons, any photons 978 00:48:45,560 --> 00:48:48,380 from X-ray emission from electrons falling down 979 00:48:48,380 --> 00:48:49,130 and energy levels. 980 00:48:49,130 --> 00:48:50,422 Yeah, Alex, you had a question? 981 00:48:50,422 --> 00:48:51,080 ALEX: Yeah. 982 00:48:51,080 --> 00:48:53,083 What are the Auger electrons? 983 00:48:53,083 --> 00:48:54,500 MICHAEL SHORT: The Auger electrons 984 00:48:54,500 --> 00:48:57,680 is that funny case where in our mental model 985 00:48:57,680 --> 00:49:01,020 a gamma ray hits an inner shell electron, 986 00:49:01,020 --> 00:49:05,120 and it's usually an inner shell electron, shooting it out. 987 00:49:05,120 --> 00:49:08,780 Then another electron will fall down 988 00:49:08,780 --> 00:49:12,660 to fill that hole emitting an X-ray. 989 00:49:12,660 --> 00:49:14,370 And the Auger process can be thought 990 00:49:14,370 --> 00:49:18,060 of that second X-ray hits an electron on the way out 991 00:49:18,060 --> 00:49:20,340 and fires out the electron. 992 00:49:20,340 --> 00:49:23,610 So this here would be the Auger electron. 993 00:49:23,610 --> 00:49:26,370 They tend to be particularly low energy. 994 00:49:26,370 --> 00:49:27,285 Yeah, Luke. 995 00:49:27,285 --> 00:49:31,602 LUKE: If you have that cascade of electrons during an electron 996 00:49:31,602 --> 00:49:35,450 capture, are they still Auger [INAUDIBLE] radiation? 997 00:49:35,450 --> 00:49:36,510 MICHAEL SHORT: Yep. 998 00:49:36,510 --> 00:49:41,070 As long as you have a higher level shell coming down 999 00:49:41,070 --> 00:49:43,230 to a lower shell and the ejection of an outer shell 1000 00:49:43,230 --> 00:49:43,730 electron. 1001 00:49:43,730 --> 00:49:46,440 That's than Auger electron emission process. 1002 00:49:46,440 --> 00:49:48,690 Regardless of whether it started with gamma 1003 00:49:48,690 --> 00:49:51,154 or started with electron capture. 1004 00:49:51,154 --> 00:49:51,654 Yep. 1005 00:49:51,654 --> 00:49:53,490 AUDIENCE: How do we know if that happens? 1006 00:49:53,490 --> 00:49:55,530 MICHAEL SHORT: You can actually sense or detect 1007 00:49:55,530 --> 00:49:57,180 the energy of those Auger electrons 1008 00:49:57,180 --> 00:50:01,100 with a very sensitive Auger electron detector. 1009 00:50:01,100 --> 00:50:03,020 These are in the sort of hundreds or thousands 1010 00:50:03,020 --> 00:50:04,855 of EV range. 1011 00:50:04,855 --> 00:50:07,022 AUDIENCE: But for like the context of this question, 1012 00:50:07,022 --> 00:50:09,380 how do we know-- 1013 00:50:09,380 --> 00:50:10,984 where would we go to find them? 1014 00:50:10,984 --> 00:50:13,067 MICHAEL SHORT: Oh, to get the Auger electron data? 1015 00:50:13,067 --> 00:50:13,810 AUDIENCE: Yeah. 1016 00:50:13,810 --> 00:50:15,477 MICHAEL SHORT: For that you can actually 1017 00:50:15,477 --> 00:50:19,990 look up the binding energies of an outer shell electron, 1018 00:50:19,990 --> 00:50:21,880 and you can do that energy balance 1019 00:50:21,880 --> 00:50:25,000 where it would be E2 minus E1. 1020 00:50:25,000 --> 00:50:26,890 Whatever the energy of that X-ray 1021 00:50:26,890 --> 00:50:34,060 is minus the binding energy of the emitted electron. 1022 00:50:34,060 --> 00:50:35,860 And because there's infinite possibilities. 1023 00:50:35,860 --> 00:50:39,280 I mean you could eject any electron, just pick one. 1024 00:50:39,280 --> 00:50:41,500 And say here's an Auger electron, 1025 00:50:41,500 --> 00:50:43,540 or draw a couple of lines in places. 1026 00:50:43,540 --> 00:50:45,935 I don't have I don't want you to get every single line. 1027 00:50:45,935 --> 00:50:47,560 If we asked you to do this for uranium, 1028 00:50:47,560 --> 00:50:50,613 there's like you know 92 electrons 1029 00:50:50,613 --> 00:50:52,030 and a lot of different transitions 1030 00:50:52,030 --> 00:50:53,810 that's not what we're going for. 1031 00:50:53,810 --> 00:50:55,518 I want to make sure you know the physics. 1032 00:50:55,518 --> 00:50:57,340 Not that you can draw 92 lines accurately 1033 00:50:57,340 --> 00:50:59,622 with a fine-toothed pencil. 1034 00:50:59,622 --> 00:51:01,240 Do you need a question two? 1035 00:51:01,240 --> 00:51:01,865 AUDIENCE: Yeah. 1036 00:51:01,865 --> 00:51:04,600 So for 2 1 if we write two possible nuclear reactions 1037 00:51:04,600 --> 00:51:07,830 for 239 on [INAUDIBLE] the right was only 1038 00:51:07,830 --> 00:51:09,580 off the case of any decision and that it's 1039 00:51:09,580 --> 00:51:12,390 a state which decay processes and repeating processes may 1040 00:51:12,390 --> 00:51:15,490 be possible for each general type of reaction. 1041 00:51:15,490 --> 00:51:16,620 What exactly does that-- 1042 00:51:16,620 --> 00:51:19,350 I find the answer for number two is alpha. 1043 00:51:19,350 --> 00:51:22,284 MICHAEL SHORT: Maybe that's the answer. 1044 00:51:22,284 --> 00:51:24,500 AUDIENCE: Oh, OK. 1045 00:51:24,500 --> 00:51:28,590 MICHAEL SHORT: And does anything compete with alpha decay? 1046 00:51:28,590 --> 00:51:32,082 Does anything compete with spontaneous fission? 1047 00:51:32,082 --> 00:51:33,880 OK. 1048 00:51:33,880 --> 00:51:34,656 Cool. 1049 00:51:34,656 --> 00:51:36,024 [INTERPOSING VOICES] 1050 00:51:36,024 --> 00:51:38,310 AUDIENCE: Is that an indication of [INAUDIBLE] 1051 00:51:38,310 --> 00:51:39,393 MICHAEL SHORT: Beta decay. 1052 00:51:39,393 --> 00:51:40,985 Well, is there-- well, for that you 1053 00:51:40,985 --> 00:51:42,360 can look up the table of nuclides 1054 00:51:42,360 --> 00:51:45,680 which I've got up here. 1055 00:51:45,680 --> 00:51:49,720 So let's take a look at plutonium 239, 1056 00:51:49,720 --> 00:51:54,560 and it precedes by alpha or spontaneous fission. 1057 00:51:54,560 --> 00:51:56,510 So every year I switch up the isotope 1058 00:51:56,510 --> 00:51:59,220 and make sure that there's at least a couple of decay modes, 1059 00:51:59,220 --> 00:52:02,220 and therefore the answers are going to change every year. 1060 00:52:02,220 --> 00:52:05,355 But the general question doesn't, 1061 00:52:05,355 --> 00:52:07,480 So this year I happened to pick an interesting one. 1062 00:52:07,480 --> 00:52:10,180 Yeah, it's kind of a mind game, right? 1063 00:52:10,180 --> 00:52:11,290 What are you missing? 1064 00:52:11,290 --> 00:52:12,040 AUDIENCE: Nothing. 1065 00:52:12,040 --> 00:52:13,140 MICHAEL SHORT: Nothing. 1066 00:52:13,140 --> 00:52:13,786 Yeah. 1067 00:52:13,786 --> 00:52:14,950 [LAUGHING] 1068 00:52:15,450 --> 00:52:18,620 Yeah, go with your physical intuition. 1069 00:52:18,620 --> 00:52:21,416 Any other questions, and maybe time for one more. 1070 00:52:21,416 --> 00:52:31,370 AUDIENCE: For 3 2, I could only find one nuclear reaction. 1071 00:52:31,370 --> 00:52:35,831 The action played after the nuclear reaction. 1072 00:52:35,831 --> 00:52:37,020 MICHAEL SHORT: Ah Yeah, 1073 00:52:37,020 --> 00:52:39,020 AUDIENCE: That's very curious you're really 1074 00:52:39,020 --> 00:52:40,237 [INAUDIBLE] decay. 1075 00:52:40,237 --> 00:52:41,070 MICHAEL SHORT: Yeah. 1076 00:52:41,070 --> 00:52:42,890 AUDIENCE: And, so I was wondering where 1077 00:52:42,890 --> 00:52:46,170 the molybdenum [INAUDIBLE] 1078 00:52:46,170 --> 00:52:47,670 MICHAEL SHORT: Yeah, so the question 1079 00:52:47,670 --> 00:52:51,720 is I specifically wrote which nuclear reactions could 1080 00:52:51,720 --> 00:52:53,790 make 99 molybdenum, despite there 1081 00:52:53,790 --> 00:52:56,740 being only one natural one. 1082 00:52:56,740 --> 00:53:00,320 So what could you induce artificially? 1083 00:53:00,320 --> 00:53:03,330 And if you can do that profitably, I'll guarantee you 1084 00:53:03,330 --> 00:53:05,130 there's a startup in it for you. 1085 00:53:05,130 --> 00:53:06,870 So what are all the different particles 1086 00:53:06,870 --> 00:53:10,260 that something could absorb to create molybdenum 99, 1087 00:53:10,260 --> 00:53:13,530 and which of those are allowable nuclear reactions? 1088 00:53:13,530 --> 00:53:15,750 And if they're not allowable, how much energy 1089 00:53:15,750 --> 00:53:18,510 do you have to put in an accelerator 1090 00:53:18,510 --> 00:53:20,550 to make that reaction happen? 1091 00:53:20,550 --> 00:53:23,370 And is the price of electricity in the accelerator 1092 00:53:23,370 --> 00:53:26,540 worth the Molly 99 that you create? 1093 00:53:26,540 --> 00:53:28,410 There are actually quite a few startups 1094 00:53:28,410 --> 00:53:29,827 working on this problem right now. 1095 00:53:29,827 --> 00:53:33,173 So the answer to this question is be creative. 1096 00:53:33,173 --> 00:53:35,340 Think about all the different particles you know of, 1097 00:53:35,340 --> 00:53:38,010 and how they could create Molly 99. 1098 00:53:38,010 --> 00:53:41,270 And figure out are any of those processes allowed, 1099 00:53:41,270 --> 00:53:43,430 and if they're not allowed, how energetic 1100 00:53:43,430 --> 00:53:45,805 do you have to make the incoming particles to allow them? 1101 00:53:47,980 --> 00:53:49,850 Ah, good question. 1102 00:53:49,850 --> 00:53:52,370 There's some creativity hiding in these problems. 1103 00:53:52,370 --> 00:53:53,360 So it's 10:02. 1104 00:53:53,360 --> 00:53:56,090 I want to cut it off here, and we'll start off Thursday 1105 00:53:56,090 --> 00:54:01,550 with a numerical example of this stuff. 1106 00:54:01,550 --> 00:54:04,240 Nuclear activation analysis.